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Titration and pH

Add alkali to acid drop by drop and watch the pH curve and indicator colour change.

  • Neutralisation
  • pH scale
  • Titration curves
0714pHvolume of alkali added (cm³)equivalenceindicator

Alkali added

0.0cm³

pH

1.00

Equivalence at

25cm³

Solution is

acidic

Predict

What is the pH at the equivalence point of a strong acid–strong alkali titration?

Experiment

  1. 1Run a strong-acid titration and read the pH at 25 cm³.
  2. 2Switch to a weak acid and compare both the starting pH and the pH at equivalence.
  3. 3Find how many cm³ it takes for the pH to travel from 4 to 10.

Explain

Neutralisation is H⁺(aq) + OH⁻(aq) → H₂O(l). As alkali is added, H⁺ ions are removed and the pH climbs — slowly at first, because plenty of acid remains.

Near the equivalence point almost no H⁺ is left, so each further drop causes a large change: the near-vertical section of the curve.

A strong acid is fully dissociated, so it starts at a much lower pH than a weak acid of the same concentration. That is a difference in dissociation, not in concentration — a distinction exam questions test constantly.